Next-gen graphene set to revolutionize nanocircuitry

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Washington, June 11 (ANI): Scientists have made an advance towards replacing silicon with graphene on nanocircuitry.

A simple and quick one-step process based on thermochemical nanolithography (TCNL) has been devised for creating nanowires, tuning the electronic properties of reduced graphene oxide on the nanoscale and thereby allowing it to switch from being an insulating material to a conducting material.

The technique works with multiple forms of graphene and is poised to become an important finding for the development of graphene electronics.

Scientists who work with nanocircuits are enthusiastic about graphene because electrons meet with less resistance when they travel along graphene compared to silicon and because today's silicon transistors are nearly as small as allowed by the laws of physics.

Graphene also has the edge due to its thickness - it's a carbon sheet that is a single atom thick.

While graphene nanoelectronics could be faster and consume less power than silicon, until now no one knew how to produce graphene nanostructures on such a reproducible or scalable method.

Elisa Riedo, associate professor in the School of Physics at the Georgia Institute of Technology, said: "We've shown that by locally heating insulating graphene oxide, both the flakes and epitaxial varieties, with an atomic force microscope tip, we can write nanowires with dimensions down to 12 nanometers. And we can tune their electronic properties to be up to four orders of magnitude more conductive. We've seen no sign of tip wear or sample tearing."

On the macroscale, the conductivity of graphene oxide can be changed from an insulating material to a more conductive graphene-like material using large furnaces.

Now, the research team used TCNL to increase the temperature of reduced graphene oxide at the nanoscale, so they can draw graphene-like nanocircuits.

They found that when it reached 130 degrees Celsius, the reduced graphene oxide began to become more conductive.

"So the beauty of this is that we've devised a simple, robust and reproducible technique that enables us to change an insulating sample into a conducting nanowire. These properties are the hallmark of a productive technology."

The research team tested two types of graphene oxide - one made from silicon carbide, the other with graphite powder.

"I think there are three things about this study that make it stand out," said William P. King, associate professor in the Mechanical Science and Engineering department at the University of Illinois at Urbana-Champaign.

He added: "First, is that the entire process happens in one step. You go from insulating graphene oxide to a functional electronic material by simply applying a nano-heater. Second, we think that any type of graphene will behave this way. Third, the writing is an extremely fast technique. These nanostructures can be synthesized at such a high rate that the approach could be very useful for engineers who want to make nanocircuits."

Walt de Heer, Regent's Professor in Georgia Tech's School of Physics and the original proponent of epitaxial graphene in electronics, said: "The simple conversion from graphene oxide to graphene is an important and fast method to produce conducting wires. This method can be used not only for flexible electronics, but it is possible, sometime in the future, that the bio-compatible graphene wires can be used to measure electrical signals from single biological cells."

The study appears in the journal Science. (ANI)

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