London, Apr 22 (ANI): By finding an experimental explanation of the phenomenon of supercooling, researchers have found why water does not freeze in the clouds.
Supercooling is a state where liquids do not solidify even below their normal freezing point and clouds in high altitude are an accumulation of supercooled droplets of water below their freezing point.
Scientists from the Commissariat a l'Energie Atomique et aux Energies Alternatives (CEA), the Centre National de Recherche Scientifique (CNRS) and the ESRF have said that supercooled liquids are trapped in a metastable state even well below their freezing point, which can only be achieved in liquids that do not contain seeds that may trigger crystallization.
Clouds at high altitude are a good example for this- they contain tiny droplets of water that, in the absence of seed crystals do not form ice despite the low temperatures.
In everyday life, though, there is usually some crystalline impurity in contact with the liquid that will trigger the crystallization process, and therefore the freezing.
Controlling solidification behaviour is important for applications ranging from hail prevention up to technological processes such as welding and casting or even the growth of semiconductor nanostructures.
Over the last 60 years the very existence of deep supercooling has led to speculations that the internal structure of liquids could be incompatible with crystallization.
Models propose that a significant fraction of the atoms in liquids arrange in five-fold coordinated clusters.
To form a crystal however, one needs a structure that can be repeated periodically, filling the entire space, which is not possible with five-fold coordinated clusters.
In the two-dimensional analogue, a plane cannot be filled by pentagons only, whereas triangles, rectangles or hexagons can fill a plane perfectly. In this example, pentagons are an obstacle to crystallization.
Until today there was no experimental proof that this five-fold coordinated structures are at the origin of supercooling.
The researchers studied the structure of a particular liquid, a gold-silicon alloy, in contact with a specially decorated silicon (111) surface, where the outermost layer of the solid featured pentagonal atomic arrangements.
Their findings confirmed that a strong supercooling effect took place.
"We studied what happened to the liquid in contact with a five-fold coordinated surface", Nature quoted Tobias Schulli, first author of the paper, as saying.
The team performed the control experiment with the same liquid exposed to three-fold and four-fold coordinated surfaces, which reduced the supercooling effect dramatically.
"This constitutes the first experimental proof that pentagonal order is at the origin of supercooling", explained Tobias Schulli.
It was during their studies, originally focusing on the growth of semiconducting nanowires, that the scientists discovered the unusual properties of these liquids.
The research is published in Nature. (ANI)